Polarization sensitive surface band structure of doped BaTiO3(001).
نویسندگان
چکیده
We present a spatial and wave-vector resolved study of the electronic structure of micron sized ferroelectric domains at the surface of a BaTiO(3)(001) single crystal. The n-type doping of the BaTiO(3) is controlled by in situ vacuum and oxygen annealing, providing experimental evidence of a surface paraelectric-ferroelectric transition below a critical doping level. Real space imaging of photoemission threshold, core level and valence band spectra show contrast due to domain polarization. Reciprocal space imaging of the electronic structure using linearly polarized light provides unambiguous evidence for the presence of both in- and out-of-plane polarization with two- and fourfold symmetry, respectively. The results agree well with first principles calculations.
منابع مشابه
Surface Effects in Ferroelectrics: Periodic Slab Computations for BaTiO3
Total energies, electronic structure, surface energies, polarization, potentials and charge densities were studied for slabs of BaTiO3 using the Linearized Augmented Plane Wave (LAPW) method. The depolarization field inhibits ferroelectricity in the slabs, and the macroscopic field set up across a ferroelectric slab is sufficient to cause electronic states to span the gap and give a metallic ba...
متن کاملElectric control of spin injection into a ferroelectric semiconductor.
Electric-field control of spin-dependent properties has become one of the most attractive phenomena in modern materials research due to the promise of new device functionalities. One of the paradigms in this approach is to electrically toggle the spin polarization of carriers injected into a semiconductor using ferroelectric polarization as a control parameter. Using first-principles density-fu...
متن کاملAb initio study of magnetoelectricity in Fe/BaTiO3: the effects of n-doped perovskite interfaces.
On the basis of ab initio calculations we study the interfacial magnetoelectric effect in a prototypical biferroic Fe(L)/XO2/BaO/BaTiO3(001) (X = Ti, V, Co), with an Fe thickness L ≤ 2 monolayers. We anticipate that the use of the n-type perovskite termination instead of nominally neutral TiO2 may enhance magnetoelectricity in the system when its magnetization is robustly changed by substrate-p...
متن کاملPeriodic Slab LAPW Computations for Ferroelectric BaTiO3
Linearized augmented plane wave (LAPW) calculations are performed for periodic (001) and (111) slabs of BaTiO3 to understand the effects of surfaces on ferroelectric BaTiO3. The (111) slab is found to be much less stable than the (001) slab. The average surface energies are respectively 3700 erg/cm and 1600 erg/cm. The depolarization field is sufficiently large in the ideal unrelaxated slab to ...
متن کاملThickness driven stabilization of saw-tooth–like domains upon phase transitions in ferroelectric thin films with depletion charges
Related Articles Correlation between growth dynamics and dielectric properties of epitaxial BaTiO3 films Appl. Phys. Lett. 100, 102904 (2012) Strong red emission in lead-free ferroelectric Pr3+-doped Na0.5Bi0.5TiO3 thin films without the need of charge compensation J. Appl. Phys. 110, 034102 (2011) Influence of thermal stresses on the electrocaloric properties of ferroelectric films Appl. Phys....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 111 12 شماره
صفحات -
تاریخ انتشار 2013